Metathesis of C5-C8 Terminal Olefins on Re2O7/Al2O3 Catalysts

被引：5

作者：

Kustov, Leonid M. ^{[1
,2
,3
]}

Furman, Daniil B. ^{[1
]}

Barkova, Aleksandra P. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prospect, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Leninskie Gory 1,Bldg 3, Moscow 119992, Russia

[3] Natl Univ Sci & Technol MISiS, Leninsky Prosp 4, Moscow, Russia

来源：

CATALYSIS LETTERS | 2016年 / 146卷 / 06期

关键词：

Metathesis; alpha-olefin C-5-C-8; Re-containing catalyst; Aluminum oxide; Olefin metathesis active site; Carbene; RHENIUM OXIDE CATALYSTS; ACTIVE-SITES; ALUMINA; GAMMA-AL2O3; ETHYLENE; SURFACE; PERFORMANCES; PROPYLENE; OXIDATION; SUPPORTS;

D O I：

10.1007/s10562-016-1698-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Primary products of the interaction of terminal olefins C-5-C-8 with Re2O7/Al2O3 catalysts are established. The rupture of the C=C bond of the olefin occurs with formation of a carbene localized at a rhenium ion, with the alkylidene fragment in the produced carbene being the CH2=group of the terminal alkene molecule. Thus M=CH2 species and lower normal alpha-olefins are formed.

引用

页码：1033 / 1039

页数：7

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