Syntheses and crystal structures of a series of palladium(II) and platinum(II) complexes bearing new hydrazine-based bisphosphinite ligands equipped with pyridyl arms

被引：5

作者：

Schaffer, Douglas J. ^{[2
]}

Batsanov, Andrei S. ^{[3
]}

Jensen, Craig M. ^{[2
]}

Takara, Satoshi ^{[1
]}

机构：

[1] Univ Ryukyus, Dept Chem Biol & Marine Sci, Okinawa 9030213, Japan

[2] Univ Hawaii Manoa, Dept Chem, Honolulu, HI 96822 USA

[3] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

POLYHEDRON | 2010年 / 29卷 / 06期

关键词：

Pt complex; Pd complex; Crystal structure; TRANSITION-METAL CHEMISTRY; MAIN-GROUP HYDRAZIDES; COORDINATION CHEMISTRY; PHOSPHORUS(III);

D O I：

10.1016/j.poly.2010.02.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper reports the synthesis of the hydrazine-based bisphosphinito ligands (RO)(2)PN(Me)N(Me)P(OR)(2) (R = 2-hydroxy-6-methyl-pyridyl or 3-hydroxy-6-methyl-pyridyl) and their palladium and platinum complexes whose structures were unequivocally determined by X-ray crystallography. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1660 / 1666

页数：7

共 11 条

[1] Inorganic backbone phosphines [J].

Appleby, T ;

Woollins, JD .

COORDINATION CHEMISTRY REVIEWS, 2002, 235 (1-2) :121-140

[2] COORDINATION CHEMISTRY OF PHOSPHORUS(III) AND PHOSPHORUS(V) HYDRAZIDES [J].

KATTI, KV ;

REDDY, VS ;

SINGH, PR .

CHEMICAL SOCIETY REVIEWS, 1995, 24 (02) :97-107

[3]

REDDY VS, 1994, CHEM BER, V127, P1355

[4] TRANSITION-METAL CHEMISTRY OF MAIN-GROUP HYDRAZIDES .16. (PHOSPHANYL)HYDRAZINES R(2)PN(ME)N(ME)PR(2) AS A NOVEL CLASS OF CHELATING BIS(PHOSPHINES) - SYNTHESIS, COORDINATION CHEMISTRY, AND X-RAY STRUCTURES OF CIS-[PDCL2((P-BRC6H4O)(2)PN-(ME)N(ME)P(OC6H4BR-P)(2))] AND CIS-[W(CO)(4)((PHO)(2)PN(ME)N(ME)P(OPH)(2))] [J].

REDDY, VS ;

KATTI, KV ;

BARNES, CL .

INORGANIC CHEMISTRY, 1995, 34 (22) :5483-5488

[5]

REDDY VS, 1994, INORG CHEM, V33, P2695

[6] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[7] Synthesis and reactivity of the ruthenium(II) dihydride Ru(Ph2PNMeNMePPh2)2H2 [J].

Shen, JY ;

Stevens, ED ;

Nolan, SP .

ORGANOMETALLICS, 1998, 17 (18) :3875-3882

[8] Synthetic and thermochemical studies of reactions of the 16-electron ruthenium complex [(Ph2PNMeNMePPh2)2RuCl]BF4 with H2, CH3CN and CO [J].

Shen, JY ;

Haar, CM ;

Stevens, ED ;

Nolan, SP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 571 (02) :205-213

[9] Enthalpies of reaction of Cp′Ru(COD)Cl (Cp′=C5H5, C5Me5, COD=cyclooctadiene) with π-acceptor chelating phosphine ligands [J].

Shen, JY ;

Stevens, ED ;

Nolan, SP .

ORGANOMETALLICS, 1998, 17 (14) :3000-3005

[10] The preparation and coordination chemistry of phosphorus(III) derivatives of dialkyl hydrazines [J].

Slawin, AMZ ;

Wainwright, M ;

Woollins, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (04) :513-519

← 1 2 →