Self-supporting soft carbon fibers as binder-free and flexible anodes for high-performance sodium-ion batteries

被引:18
作者
Gao, Xueping [1 ]
An, Yongling [1 ]
Zhang, Wenshu [1 ]
Yu, Menglan [1 ]
Ci, Lijie [1 ]
Feng, Jinkui [1 ]
机构
[1] Shandong Univ, SDU & Rice Joint Ctr Carbon Nanomat, Key Lab Liquid Solid Struct Evolut & Proc Mat, Minist Educ,Sch Mat Sci & Engn, Jinan 250061, Shandong, Peoples R China
关键词
Soft carbon fiber; binder-free; flexible anodes; sodium-ion batteries; HARD-CARBON; LITHIUM-ION; INSERTION; STORAGE; NANOFIBERS; ELECTRODES;
D O I
10.1080/10667857.2018.1509525
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sodium batteries are considered as the most promising candidates for next generation power source. Carbon materials are the most viable anode material for sodium ion batteries. However, graphic soft carbons, the most widely used anodes in lithium ion batteries due to its higher electronic conductivity and density, are fail to work in sodium ion batteries due to the larger Na+ radius. Here, in our reports, soft carbon fibers derived from industrialized wet spun polyacrylonitrile (PAN) precursor are fabricated under different heat treatment temperature. When characterized as binder and conductive agent free anode for sodium ion batteries, the soft carbon fibers (1250 degrees C) deliver an initial reversible capacity 190 mAh g(-1) and a good capacity retention of 93% even after 100 cycles. The excellent electrochemical performance makes the soft carbon fibers promising choices as anodes for sodium ion batteries.
引用
收藏
页码:810 / 814
页数:5
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