Superstructure of tetragonal BaGd2Mn2O7

被引:7
作者
Kamegashira, N [1 ]
Satoh, H [1 ]
Mikami, T [1 ]
机构
[1] Toyohashi Univ Technol, Dept Mat Sci, Toyohashi, Aichi 4418580, Japan
关键词
crystal structure; oxygen octahedron; barium gadolinium manganese oxide;
D O I
10.1016/S0925-8388(00)00864-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The crystal structure of a layered perovskite compound, BaGd2Mn2O7, was analyzed for the powder X-ray diffraction data by Rietveld method. The tetragonal BaGd2Mn2O7 phase has superlattice lines so that the space group of P4(2)/mnm (No. 136) was determined with the unit cell dimensions a=0.55014(1) and c=2.02457(5) nm. The MnO6 octahedron was distorted and tilts by 6 degrees apart from the c axis mutually in the reverse direction. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:69 / 73
页数:5
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