Synthesis of Fluorinated Imines by Addition of Fluoroalkyl Radicals to Conjugated Imines

被引：12

作者：

Ueda, Masafumi ^{[1
]}

Iwasada, Eri ^{[1
]}

Miyabe, Hideto ^{[2
]}

Miyata, Okiko ^{[1
]}

Naito, Takeaki ^{[1
]}

机构：

[1] Kobe Pharmaceut Univ, Higashinada Ku, Kobe, Hyogo 6588558, Japan

[2] Hyogo Univ Hlth Sci, Sch Pharm, Chuo Ku, Kobe, Hyogo 6508530, Japan

来源：

SYNTHESIS-STUTTGART | 2010年 / 12期

关键词：

imines; fluoro compounds; addition reactions; radical reactions; fluoroalkylimines; CARBON-CENTERED RADICALS; PERFLUOROALKYL IODIDES; ASYMMETRIC-SYNTHESIS; ALKYL RADICALS; AMINO-ACIDS; TRIFLUOROMETHYLATION; CHEMISTRY; ALDEHYDES; BOND;

D O I：

10.1055/s-0029-1218755

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel preparation of beta-perfluoroalkyl imine derivatives, useful as synthetic building blocks, was achieved by a route involving addition of electrophilic fluoroalkyl radicals to alpha,beta-unsaturated imines.

引用

页码：1999 / 2004

页数：6

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