Synthesis of Microporous Carbon Foams as Catalyst Supports

被引：33

作者：

Glenk, Friedrich ^{[1
]}

Knorr, Tilman ^{[1
]}

Schirmer, Matthias ^{[1
]}

Guetlein, Stefan ^{[1
]}

Etzold, Bastian J. M. ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Chair Chem React Engn, D-91058 Erlangen, Germany

来源：

CHEMICAL ENGINEERING & TECHNOLOGY | 2010年 / 33卷 / 04期

关键词：

Carbide-derived carbon; CDC method; Foams; Microporous carbon; CARBIDE-DERIVED CARBONS; HYDROGEN STORAGE; ACTIVATED CARBON; MONOLITHS; NITROBENZENE; POROSITY; REACTOR;

D O I：

10.1002/ceat.201000005

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Microporous carbon foams were synthesized as structured catalyst supports by the carbide-derived carbon (CDC) method. The self-supporting foams showed a narrow pore size distribution which seems to induce shape-selective effects during reactions. The applicability of these materials as supports for active metals was tested in a hydrogenation reaction of different olefins with a CDC powder wet impregnated with platinum.

引用

页码：698 / 703

页数：6

共 25 条

[1] Concept study: structured trickling bed reactor [J].

Bauer, Tobias ;

Haase, Stefan ;

Lange, Ruediger .

CHEMIE INGENIEUR TECHNIK, 2009, 81 (07) :989-994

[2] Ceramic foam monoliths as catalyst carriers. 1. Adjustment and description of the morphology [J].

Buciuman, FC ;

Kraushaar-Czarnetzki, B .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (09) :1863-1869

[3] Starbons: New starch-derived mesoporous carbonaceous materials with tunable properties [J].

Budarin, Vitaly ;

Clark, James H. ;

Hardy, Jeffrey J. E. ;

Luque, Rafael ;

Milkowski, Krzysztof ;

Tavener, Stewart J. ;

Wilson, Ashley J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (23) :3782-3786

[4] Carbonized wood monoliths - Characterization [J].

Byrne, CE ;

Nagle, DC .

CARBON, 1997, 35 (02) :267-273

[5] Synthesis, structure and porosity analysis of microporous mesoporous carbon derived from zirconium carbide [J].

Dash, RK ;

Yushin, G ;

Gogotsi, Y .

MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 86 (1-3) :50-57

[6] Nanoporous carbide-derived carbon with tunable pore size [J].

Gogotsi, Y ;

Nikitin, A ;

Ye, HH ;

Zhou, W ;

Fischer, JE ;

Yi, B ;

Foley, HC ;

Barsoum, MW .

NATURE MATERIALS, 2003, 2 (09) :591-594

[7] Tailoring of nanoscale porosity in carbide-derived carbons for hydrogen storage [J].

Gogotsi, Y ;

Dash, RK ;

Yushin, G ;

Yildirim, T ;

Laudisio, G ;

Fischer, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (46) :16006-16007

[8] Carbon coatings on silicon carbide by reaction with chlorine-containing gases [J].

Gogotsi, YG ;

Jeon, ID ;

McNallan, MJ .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (09) :1841-1848

[9] Functional carbonaceous materials from hydrothermal carbonization of biomass: an effective chemical process [J].

Hu, Bo ;

Yu, Shu-Hong ;

Wang, Kan ;

Liu, Lei ;

Xu, Xue-Wei .

DALTON TRANSACTIONS, 2008, (40) :5414-5423

[10] Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability [J].

Hu, Yong-Sheng ;

Adelhelm, Philipp ;

Smarsly, Bernd M. ;

Hore, Sarmimala ;

Antonietti, Markus ;

Maier, Joachim .

ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (12) :1873-1878

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