Cyclopentadienyl zincates:: Synthesis and x-ray studies of sodium and potassium salts of the [Zn(C5H5)3]- and [Zn2(C5H5)5]- ions

被引：22

作者：

Alvarez, Eleuterio ^{[1
]}

Grirrane, Abdessamad ^{[1
]}

Resa, Irene ^{[1
]}

del Rio, Diego ^{[1
]}

Rodriguez, Amor ^{[1
]}

Carmona, Ernesto ^{[1
]}

机构：

[1] Univ Seville, CSIC, Inst Invest Quim, Dept Quim Organ, Seville 41092, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 08期

关键词：

alkali metals; density functional calculations; metallocenes; structure elucidation; zinc;

D O I：

10.1002/anie.200603875

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zigzag zinc: The Na+ and K+ salts of the [Zn(C 5H5)3]- ion exhibit polymeric 1D and 2D structures, respectively. In contrast, the dizincate [Na(thf) 6][Zn2(C5H5)5] contains discrete [Zn2(C5H5)5]- ions that consist of two {Zn(C5H5)2} groups with η1(π)/η1(π) binding, bridged by a C5H5 ring η1(π)-coordinated to each zinc atom (see structure). (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1296 / 1299

页数：4

共 51 条

[1] THE MOLECULAR-STRUCTURES OF DIMETHYL-ZINC, DIETHYL-ZINC AND DIPROPYLZINC DETERMINED BY GAS-PHASE ELECTRON-DIFFRACTION - NORMAL COORDINATE ANALYSIS AND ABINITIO MOLECULAR-ORBITAL CALCULATIONS ON DIMETHYLZINC
ALMENNINGEN, A
HELGAKER, TU
HAALAND, A
SAMDAL, S
[J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1982, 36 (02): : 159 - 166
[2] Structural and magnetic studies of the tris(cyclopentadienyl)manganese(II) "paddle-wheel" anions [CP3-n(MeCp)nMn]- (n=0-3, MeCp=C5H4CH3, CP=C5H5)
Alvarez, CS
Bashall, A
McInnes, EJL
Lafield, RA
Mole, RA
McPartlin, M
Rawson, JM
Wood, PT
Wright, DS
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (11) : 3053 - 3060
[3] AMSTRONG DR, 1997, ORGANOMETALLICS, V16, P3340
[4] ADDUCTS OF CYCLOPENTADIENYL SODIUM AND METHYLCYCLOPENTADIENYL SODIUM WITH OXYGEN BASES AND NITROGEN BASES - STRUCTURE OF CYCLOPENTADIENYLSODIUMTETRAMETHYLETHYLENEDIAMINE, NA(C5H5)(ME2NCH2CH2NME2)
AOYAGI, T
SHEARER, HMM
WADE, K
WHITEHEAD, G
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 175 (01) : 21 - 31
[5] Crystallization and X-ray structures of [NaYb(C5H5)(3)] and Yb(C5H5)(2)
Apostolidis, C
Deacon, GB
Dornberger, E
Edelmann, FT
Kanellakopulos, B
MacKinnon, P
Stalke, D
[J]. CHEMICAL COMMUNICATIONS, 1997, (11) : 1047 - 1048
[6] Adducts of carbenes with group II and XII metallocenes
Arduengo, AJ
Davidson, F
Krafczyk, R
Marshall, WJ
Tamm, M
[J]. ORGANOMETALLICS, 1998, 17 (15) : 3375 - 3382
[7] Alkali-metal-mediated zineation of ferrocene: Synthesis, structure, and reactivity of a lithium tmp/zincate reagent
Barley, HRL
Clegg, W
Dale, SH
Hevia, E
Honeyman, GW
Kennedy, AR
Mulvey, RE
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (37) : 6018 - 6021
[8] BARLEY HRL, 2005, ANGEW CHEM, V117, P6172
[9] SYNTHESIS, CHARACTERIZATION, AND CRYSTAL AND MOLECULAR-STRUCTURE OF TRICYCLOPENTADIENYLGALLIUM(III)
BEACHLEY, OT
GETMAN, TD
KIRSS, RU
HALLOCK, RB
HUNTER, WE
ATWOOD, JL
[J]. ORGANOMETALLICS, 1985, 4 (04) : 751 - 754
[10] Beattie J.K., 1992, INORG CHIM ACTA, V309, P198

← 1 2 3 4 5 6 →