Structure and binding properties of water-soluble cavitands and capsules

被引：363
作者：
Biros, Shannon M. [1 ]
Rebek, Julius, Jr. [1 ]
机构：
[1] Scripps Res Inst, Skaggs Inst Chem Biol, Dept Chem, 10550 N Torrey Pines Rd,MB26, La Jolla, CA 92037 USA
来源：
CHEMICAL SOCIETY REVIEWS | 2007年 / 36卷 / 01期
关键词：
D O I：
10.1039/b508530f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synthetic receptors are modern tools for investigations into the forces involved in recognition. A widely exploited class of receptors are the resorcin[4]arene-based cavitands and capsules. This critical review (71 references) describes the evolution of water-soluble versions of these structures, along with insights the resulting host-ndash complexes have provided with regard to complexation driving forces in water. An emphasis has been placed on the influence of host structure on guest affinity and dynamics.
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页码：93 / 104
页数：12
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