Kinetics, mathematical modeling, and optimization of the oxidative coupling of methane over a LiMnW/SiO2 catalyst

被引：18

作者：

Dedov, A. G. ^{[1
]}

Makhlin, V. A. ^{[2
]}

Podlesnaya, M. V. ^{[2
]}

Zyskin, A. G. ^{[2
]}

Loktev, A. S. ^{[1
]}

Tyunjaev, A. A. ^{[1
]}

Nipan, G. D. ^{[3
]}

Koltsova, T. N. ^{[3
]}

Ketsko, V. A. ^{[3
]}

Kartasheva, M. N. ^{[1
]}

Moiseev, I. I. ^{[1
]}

机构：

[1] Russian State Univ Oil & Gas, Moscow, Russia

[2] Russian Acad Sci, Inst Petrochem Synth, Moscow, Russia

[3] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING | 2010年 / 44卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

Kinetic parameters;

D O I：

10.1134/S004057951001001X

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A phenomenological kinetic model is developed, and the numerical values of the kinetic parameters of the oxidative coupling of methane that is catalyzed by a new LiMnW/SiO2 composite material are determined. The mathematical modeling of the process is performed, and the optimal conditions and approaches to the apparatus-technological design of the process are determined.

引用

页码：1 / 11

页数：11

共 12 条

[1] Kinetics of a gas-phase chain reaction catalyzed by a solid: The oxidative coupling of methane over Li/MgO-based catalysts [J].