Bistable N-H•••N hydrogen bonds for reversibly modulating the dynamic motion in an organic co-crystal

被引：21

作者：

Ji, Chengmin ^{[1
]}

Li, Shenhui ^{[2
]}

Deng, Feng ^{[2
]}

Liu, Sijie ^{[1
]}

Asghar, Muhammad Adnan ^{[1
]}

Sun, Zhihua ^{[1
]}

Hong, Maochun ^{[1
]}

Luo, Junhua ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom Mol Phys, Wuhan 430071, Peoples R China

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2016年 / 18卷 / 16期

基金：

中国国家自然科学基金;

关键词：

PHASE-TRANSITION; MOLECULAR ROTORS; ROTATIONAL-DYNAMICS; TWISTING MOTION; METAL; FERROELECTRICITY; CONDUCTORS; BEHAVIOR;

D O I：

10.1039/c6cp01073c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Bistable N-H center dot center dot center dot N hydrogen bonds between rotors and stators enable delicate modulation of dynamic molecular motion by slowing down the fast rotation in a N-H center dot center dot center dot N hydrogen-bonded organic co-crystal of 1,2-diazabicyclo(2.2.2)octane bis(thiourea), which has been elucidated by the combination of variable-temperature (VT) X-ray structure analyses and VT solid-state nuclear magnetic resonance techniques.

引用

页码：10868 / 10872

页数：5

共 45 条

[1] Molecular rotor of Cs2([18]crown-6)3 in the solid state coupled with the magnetism of [Ni(dmit)2] [J].