Chemical kinetics of the reaction between carbon dioxide and phenyl glycidyl ether using Aliquat 336 as a catalyst

被引：15

作者：

Park, SW ^{[1
]}

Park, DW ^{[1
]}

Kim, TY ^{[1
]}

Park, MY ^{[1
]}

Oh, KJ ^{[1
]}

机构：

[1] Pusan Natl Univ, Div Chem Engn, Pusan 609735, South Korea

来源：

CATALYSIS TODAY | 2004年 / 98卷 / 04期

关键词：

chemical absorption; carbon dioxide; PGE; Aiquat; 336;

D O I：

10.1016/j.cattod.2004.09.002

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The kinetics of the reaction of carbon dioxide with phenyl glycidyl ether using Aliquat 336 as a catalyst in such nonaqueous solvents as toluene, N-methyl-2-pirrolidinone and dimethyl sulfoxide were studied using a stirred tank absorber with a plane gas-liquid interface at 358 and 0.1013 MPa. A mathematical model accompanied by a chemical absorption mechanism of carbon dioxide was presented to obtain the values of the rate parameters for which the predicted rate of absorption of CO2 matched the experimental value. The relationship between the rate parameter and the solubility parameter of the solvent was presented. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：493 / 498

页数：6

共 15 条

[1] ACTIVATION OF CARBON-DIOXIDE WITH ALUMINUM PORPHYRIN AND REACTION WITH EPOXIDE - STUDIES ON (TETRAPHENYLPORPHINATO)ALUMINUM ALKOXIDE HAVING A LONG OXYALKYLENE CHAIN AS THE ALKOXIDE GROUP [J].