Synthesis of benzyl alcohol by indirect electrochemical catalyzed oxidation of toluene in basic methanol solvent

被引：16

作者：

Ma, HZ

Wang, B ^{[1
]}

Liang, YQ

机构：

[1] Shaanxi Normal Univ, Coll Chem & Mat Sci, Xian 710062, Peoples R China

[2] NW Univ Xian, Dept Chem, Xian 710068, Shaanxi, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2004年 / 5卷 / 10期

关键词：

electrolysis; toluene; current intensity; electrochemical oxidation;

D O I：

10.1016/j.catcom.2004.07.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Benzyl alcohol detected by gas chromatography/mass spectrometry was obtained in high yields (78.3%) from the electrolysis of toluene at constant current intensity in basic methanol. The effect of the medium was investigated by UV spectrum. A possible reaction mechanism was proposed. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：617 / 620

页数：4

共 7 条

[1] Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin [J].