Synthesis of a neutral S-P-S pincer Pd(II) complex with the proligand PhP(C6H4-SH-2)2 [phPS2H2].: The X-ray crystal structure of [Pd(phPS2)(PPh3)]

被引：25

作者：

Gómez-Benítez, V ^{[1
]}

Hernández-Ortega, S ^{[1
]}

Morales-Morales, D ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Coyoacan 04510, DF, Mexico

来源：

INORGANICA CHIMICA ACTA | 2003年 / 346卷

关键词：

crystal structures; palladium complexes; P; S-proligands complexes; pincer ligands complexes;

D O I：

10.1016/S0020-1693(02)01372-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of the hybrid phosphorus-sulfur proligand phPS(2)H(2) with the trans -[Pd(Cl)(2)(PPh3)(2)] precursor has been explored. By reacting trans -[Pd(Cl)(2)(PPh3)(2)] with phPS(2)H(2) in the presence of NEt3 as base, the complex [Pd(phPS(2))(PPh3)] was obtained. A single crystal X-ray structure determination for [Pd(phPS(2))(PPh3)] shown the compound to be square planar with the ligand phPS(2) behaving as a S-P-S pincer ligand. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：256 / 260

页数：5

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