X-ray diffraction and Raman spectroscopy study of white decorations on tricolored ceramics from Northwestern Argentina

被引：15

作者：

Freire, E. ^{[1
,2
,3
]}

Acevedo, V. ^{[4
]}

Halac, E. B. ^{[1
,2
]}

Polla, G. ^{[1
]}

Lopez, M. ^{[3
,4
]}

Reinoso, M. ^{[1
,2
,3
]}

机构：

[1] Comis Nacl Energia Atom, Ctr Atom Constituyentes, Avda Gen Paz 1499,B1650KNA, V Maipu, Pcia Buenos Air, Argentina

[2] Univ Nacl San Martin, Escuela Ciencia & Tecnol, Martin de Irigoyen 3700, RA-1650 Gral San Martin, Pcia Buenos Air, Argentina

[3] Consejo Nacl Invest Cient & Tecn, Godoy Cruz 2290,C1425FQB, Ca Buenos Aires, Argentina

[4] Univ Buenos Aires, Fac Filosofia & Letras, Inst Arqueol, 25 Mayo 217 C1002ABE, Buenos Aires, DF, Argentina

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2016年 / 157卷

关键词：

XRD; Raman spectroscopy; Archaeological ceramics; White decorations; NW Argentina; OXIDES; FTIR;

D O I：

10.1016/j.saa.2015.12.030

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

White virgules, commas, and dot designs on tricolored ceramics are sporadically found in different archaeological sites located in Northwestern Argentina area, as Puna and Quebrada de Humahuaca. This decorating style has been reported in several articles, but few previous archaeometric studies have been carried out on the pigment composition. Fragments from Puna and Quebrada archaeological sites, belonging to Regional Development Period (9001430 AD), were analyzed by X-ray diffraction and Raman spectroscopy in order to characterize the pigments employed. Red and black pigments are based on iron and manganese oxides, as it has been extensively reported for the NW Argentina area. White pigments from white virgules, comma, and dot designs have shown different composition. Hydroxyapatite was found in samples from Doncellas site (North Puna region), and calcium and calcium -magnesium containing compounds, as vaterite and dolomite, along with titanium containing compounds were detected on samples from Abralaite (Central Puna region) and Gasoducto (Quebrada de Humahuaca region). It has been concluded that pigment composition is not characteristic of a unique region. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：182 / 185

页数：4

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