The mechanism of sulfur release and reaction with calcium during corn straw and coal co-combustion

被引：0

作者：

Yang, Tianhua ^{[1
]}

Kai, Xingping ^{[2
]}

Sun, Yang ^{[2
]}

Li, Rundong ^{[2
]}

机构：

[1] Shenyang Inst Aeronaut Engn, Inst Clean Energy & Environm Engn, Shenyang, Peoples R China

[2] Shenyang Inst Aeronaut Engn, Liaoning Key Lab Clean Energy, Shenyang, Peoples R China

来源：

ICEET: 2009 INTERNATIONAL CONFERENCE ON ENERGY AND ENVIRONMENT TECHNOLOGY, VOL 1, PROCEEDINGS | 2009年

基金：

中国国家自然科学基金;

关键词：

coal; corn straw; co-combustion; calcium oxygen; desulfurization; BIOMASS;

D O I：

10.1109/ICEET.2009.222

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The mechanism of sulfur retention by alkali and specific earth metals of corn straw and coal were experimentally investigated using thermogravimetric analyzer (TG) and gas chromatography and mass spectrometer (GC-MS), as well as the effects of different concentration of oxygen on alkali earth metal CaO sulfate. The results show that the existence of alkali metals can catalyze volatile content and coke combustion and react with SO2 to form steady sulfate. The desulfurization process of alkaline minerals is mainly divided into three phases: physical adsorption stage, chemical reaction control stage and diffusion resistance control stage, a single alkaline-earth metal CaO consistent with that. For the certain amount of desulfurization agent of CaO particles, the sulfate is not affected by the concentration of oxygen in the oxygen-rich conditions.

引用

页码：897 / +

页数：2

共 5 条

[1] Sustainable cofiring of biomass with coal [J].

Demirbas, A .

ENERGY CONVERSION AND MANAGEMENT, 2003, 44 (09) :1465-1479

[2]

Mi Tie, 2004, ACTA ENERGIAE SOLARI, V25, P236

[3] Release of K, Cl, and S species during co-combustion of coal and straw [J].

Mueller, Michael ;

Wolf, Karl-Josef ;

Smeda, Agnieszka ;

Hilpert, Klaus .

ENERGY & FUELS, 2006, 20 (04) :1444-1449

[4] Measurement and prediction of the emission of pollutants from the combustion of coal and biomass in a fixed bed furnace [J].

Ross, AB ;

Jones, JM ;

Chaiklangmuang, S ;

Pourkashanian, M ;

Williams, A ;

Kubica, K ;

Andersson, JT ;

Kerst, M ;

Danihelka, P ;

Bartle, KD .

FUEL, 2002, 81 (05) :571-582

[5]

[周俊虎 Zhou Junhu], 2005, [燃料化学学报, Journal of Fuel Chemistry and Technology], V33, P626

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