The reactivity of an anionic gallium N-heterocyclic carbene analogue with a solution stable digermene

被引：15
|
作者：
Rupar, Paul A. [1 ]
Jennings, Michael C. [1 ]
Baines, Kim M. [1 ]
机构：
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2007年 / 85卷 / 02期
关键词：
digermene; carbene analogue; germylene; gallium(I);
D O I：
10.1139/V07-002
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of the anionic gallium(I) N-heterocyclic carbene (NHC) analogue 3 with the solution stable digermene 5 results in the formation of the gallium NHC - germylene complex 8. The gallium NHC - germylene complex 8 was derivatized with CH3I and (CH3)(3)SiCl.
引用
收藏
页码：141 / 147
页数：7
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