[Ge8{N(SiMe3)2)6]:: A ligand-stabilized Ge cluster compound with formally zero-valent Ge atoms

被引：59
作者：
Schnepf, A [1 ]
Köppe, R [1 ]
机构：
[1] Univ Karlsruhe, TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 08期
关键词：
D O I：
10.1002/anie.200390241
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Starting from germanium(I) bromide, which can be obtained by preparative co-condensation, the first polyhedral Ge cluster [Ge8{N(SiMe3)2}6] (see picture) has been synthesized in which the average oxidation state of all the Ge atoms in the cluster core lies between 0 and + 1.
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页码：911 / +
页数：4
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