Investigation on the structure and the oxidation activity of the solid carbon produced from catalytic decomposition of methane

被引：37

作者：

Chen, Jiuling ^{[1
]}

Yang, Xue ^{[1
]}

Li, Yongdan ^{[1
]}

机构：

[1] Tianjin Univ, Tianjin Key Lab Appl Catalysis Sci & Technol, Sch Chem Engn, Tianjin 300072, Peoples R China

来源：

FUEL | 2010年 / 89卷 / 05期

关键词：

Catalytically-grown solid carbon; Graphitization degree; Average oxidation temperature; GRAPHITE FIBERS; FUEL-CELLS; RAMAN-SPECTROSCOPY; NANOTUBES; HYDROGEN; NANOFIBERS; CONVERSION; FILAMENTS; NICKEL; GROWTH;

D O I：

10.1016/j.fuel.2009.08.017

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The structure and the oxidation activity of the solid carbon produced from catalytic decomposition of methane at different temperatures were investigated using TEM, XRD, Raman and TPO techniques. The results show that the graphitization degree of the solid carbon is increased with decomposition reaction temperature. The addition of ethylene or acetylene to methane can change the growth way of the solid carbon and decrease their graphitization degree. The average oxidation temperature of the solid carbon has a close relationship with the corresponding graphitization degree. The addition of ethylene or acetylene to methane can decrease the average oxidation temperature of the solid carbon. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：943 / 948

页数：6

共 32 条

[1] NUCLEATION AND GROWTH OF CARBON DEPOSITS FROM NICKEL CATALYZED DECOMPOSITION OF ACETYLENE [J].