Synthesis of a series of glucosyl triazole derivatives and their self-assembling properties

被引：28

作者：

Mangunuru, Hari P. R. ^{[1
]}

Yerabolu, Jayasudhan R. ^{[1
]}

Liu, Dong ^{[1
]}

Wang, Guijun ^{[1
]}

机构：

[1] Old Dominion Univ, Dept Chem & Biochem, Norfolk, VA 23529 USA

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 01期

基金：

美国国家科学基金会;

关键词：

Hydrogelators; Organogelators; Self-assembly; Click reaction; Glucose; Triazole; MOLECULAR-WEIGHT GELATORS; CLICK CHEMISTRY; CARBOHYDRATE-CHEMISTRY; SUPRAMOLECULAR HYDROGELATORS; DRUG-DELIVERY; AMINO-ACID; CYCLOADDITION; ORGANOGELS; GELATION; DESIGN;

D O I：

10.1016/j.tetlet.2014.11.013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report the synthesis and self-assembling properties of a new class of glucosyl triazole derivatives from glucose. The compounds are synthesized by a Cu(I) catalyzed azide/alkyne cycloaddition reaction, or the 'click' reaction. Several efficient low molecular weight organogelators were obtained in this study. We found that triazole analogs containing long alkyl hydroxyl groups and phenyl groups typically are effective in forming supramolecular gels. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：82 / 85

页数：4

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