Design, synthesis and structural investigation of a 2-D coordination network based on the self-assembly of the tetracarboxylate derivative of tetrathiacalix[4]arene and silver cation

被引：88

作者：

Akdas, H

Graf, E

Hosseini, MW ^{[1
]}

De Cian, A

Harrowfield, JM

机构：

[1] Univ Strasbourg 1, Chim Coordinat Organ Lab, CNRS, UMR 7513, F-67000 Strasbourg, France

[2] Univ Western Australia, Nedlands, WA 6009, Australia

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 22期

关键词：

D O I：

10.1039/b007761p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The fully deprotonated tetrathiacalix[4]arene 1(4-) in 1,3-alternate conformation and bearing four carboxylate units was shown to act as a tecton leading, in the presence of Ag+ cation, to a 2-D coordination network in the crystalline phase which can be described as discrete binuclear [1(4-), (Ag+)(2)](2-) complexes interconnected by Ag+ cations.

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收藏

页码：2219 / 2220

页数：2

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