Design, synthesis and structural investigation of a 2-D coordination network based on the self-assembly of the tetracarboxylate derivative of tetrathiacalix[4]arene and silver cation

被引：88
|
作者：
Akdas, H
Graf, E
Hosseini, MW [1 ]
De Cian, A
Harrowfield, JM
机构：
[1] Univ Strasbourg 1, Chim Coordinat Organ Lab, CNRS, UMR 7513, F-67000 Strasbourg, France
[2] Univ Western Australia, Nedlands, WA 6009, Australia
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 22期
关键词：
D O I：
10.1039/b007761p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The fully deprotonated tetrathiacalix[4]arene 1(4-) in 1,3-alternate conformation and bearing four carboxylate units was shown to act as a tecton leading, in the presence of Ag+ cation, to a 2-D coordination network in the crystalline phase which can be described as discrete binuclear [1(4-), (Ag+)(2)](2-) complexes interconnected by Ag+ cations.
引用
收藏
页码：2219 / 2220
页数：2
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