The bis(η-cyclopentadienyl)titanium(IV) -: salicylate system revisited and the characterisation of two 3,5-di-t-butylsalicylate analogues.: The molecular structure of [Cp2Ti(sal)], (sal = O2CC6H4O2-)

被引：16

作者：

Edwards, DA ^{[1
]}

Mahon, MF ^{[1
]}

Paget, TJ ^{[1
]}

Summerhill, NW ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

TRANSITION METAL CHEMISTRY | 2001年 / 26卷 / 1-2期

关键词：

D O I：

10.1023/A:1007184425487

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Cp2TiIV - salicylate system has been re-examined and procedures for the syntheses of [Cp2Ti(salH)(2)] and [Cp2Ti(sal)] explored, [salH = (O2CC6H4OH-2)(-); sal = (O2CC6H4O-2)(2-)]. The new 3,5-di-t-butylsalicylate analogues have been prepared and characterised. An X-ray structure determination of [Cp2Ti(sal)] confirms the chelating nature of the sal ligand which is bonded to the metal through the phenolic and one of the carboxylate oxygen atoms.

引用

页码：116 / 119

页数：4

共 38 条

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