The bis(η-cyclopentadienyl)titanium(IV) -: salicylate system revisited and the characterisation of two 3,5-di-t-butylsalicylate analogues.: The molecular structure of [Cp2Ti(sal)], (sal = O2CC6H4O2-)

被引：16

作者：

Edwards, DA ^{[1
]}

Mahon, MF ^{[1
]}

Paget, TJ ^{[1
]}

Summerhill, NW ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

TRANSITION METAL CHEMISTRY | 2001年 / 26卷 / 1-2期

关键词：

D O I：

10.1023/A:1007184425487

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Cp2TiIV - salicylate system has been re-examined and procedures for the syntheses of [Cp2Ti(salH)(2)] and [Cp2Ti(sal)] explored, [salH = (O2CC6H4OH-2)(-); sal = (O2CC6H4O-2)(2-)]. The new 3,5-di-t-butylsalicylate analogues have been prepared and characterised. An X-ray structure determination of [Cp2Ti(sal)] confirms the chelating nature of the sal ligand which is bonded to the metal through the phenolic and one of the carboxylate oxygen atoms.

引用

页码：116 / 119

页数：4

共 38 条

[1] The bis(η-cyclopentadienyl)titanium(IV) – salicylate system revisited and the characterisation of two 3,5-di-t-butylsalicylate analogues. The molecular structure of [Cp2Ti(sal)], (sal = O2CC6H4O2−)
Dennis A. Edwards
Mary F. Mahon
Timothy J. Paget
Nicholas W. Summerhill
Transition Metal Chemistry, 2001, 26 : 116 - 119
[2] Molecular precursors for ferroelectric materials:: Synthesis and characterization of Bi2M2(μ-O)(sal)4(Hsal)4(OEt)2 and BiM4(μ-O)4(sal)4(Hsal)3(OiPr)4 (sal = O2CC6H4O, Hsal = O2CC6H4OH) (M = Nb, Ta)
Thurston, JH
Whitmire, KH
INORGANIC CHEMISTRY, 2003, 42 (06) : 2014 - 2023
[3] Heterobimetal lic bismuth-transition metal salicylate complexes as molecular precursors for ferroelectric materials.: Synthesis and structure of Bi2M2(sal)4(Hsal)4(OR) 4 (M = Nb, Ta; R = CH2CH3, CH(CH3)2), Bi2Ti3(sal)8(Hsal)2, and Bi2Ti4(OiPr)(sal)10(Hsal) (sal = O2CC6H4-2-O; Hsal = O2CC6H4-2-OH)
Thurston, JH
Whitmire, KH
INORGANIC CHEMISTRY, 2002, 41 (16) : 4194 - 4205
[4] CRYSTAL AND MOLECULAR STRUCTURES OF BIS （CYCLOPENTADIENYL） BIS （2,4,6-TRICHLOROPHENOXY）TITANIUM, Cp2Ti（OC6H2Cl3-2,4,6）2 （Ⅰ） AND TETRAKIS（CYCLOPENTADIENYL）BIS （4-CHLOROPHENOXY）-μ-OXO-DIZIRCONIUM,[Cp2Zr（OC6H4Cl-p）]2O （Ⅱ）
杨清传
金祥林
徐筱杰
李根培
唐有祺
陈寿山
Science in China,SerB., 1982, Ser.B.1982 (04) : 356 - 366
[5] CRYSTAL AND MOLECULAR-STRUCTURES OF BIS (CYCLOPENTADIENYL) BIS (2,4,6-TRICHLOROPHENOXY) TITANIUM, CP2TI (OC6H2CL3-2,4,6)2 (I) AND TETRAKIS(CYCLOPENTADIENYL) BIS (4-CHLOROPHENOXY)-MU-OXO-DIZIRCONIUM, [CP2ZR(OC6H4CL-P)]2O (II)
YANG, QC
JIN, XL
XU, XJ
LI, GP
TANG, YQ
CHEN, SS
SCIENTIA SINICA SERIES B-CHEMICAL BIOLOGICAL AGRICULTURAL MEDICAL & EARTH SCIENCES, 1982, 25 (04) : 356 - 366
[6] SYNTHESIS AND CHARACTERIZATION OF GROUP-IV METAL IRON COMPLEXES BRIDGED BY CARBOXYLATE SUBSTITUTED CYCLOPENTADIENYL GROUP - THE STRUCTURE OF CP2TI[(MU-O2CC5H4)FE(CO)2(CH2C6H5)]2
GAU, HM
SCHEI, CC
LIU, LK
LUH, LH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 435 (1-2) : 43 - 53
[7] Syntheses and spectra of chromium-titanium complexes bridged by carboxylate substituted cyclopentadienyl group:: The structure of CP2Ti(CH3){[OC(O)C5H4]Cr(NO)2Cl}
Wang, Yu-Pin
Pang, Su-Ru
Cheng, Hsiu-Yao
Lin, Tso-Shen
Wang, Yu
Lee, Gene-Hsiang
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (02) : 329 - 337
[8] Synthesis and characterization of new titanium hexanuclear oxo carboxylato alkoxides.: Molecular structure of [Ti6(μ3-O)6-(μ-O2CC6H4OPh)6(OEt)6]
Papiernik, R
Hubert-Pfalzgraf, LG
Vaissermann, J
Goncalves, MCHB
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (14): : 2285 - 2287
[9] Crystal structure of bis[(4-tert-butylbenzoato-κ2O,O)-(4-tert-butylbenzoato-κO)]lead(IV), Pb[(CH3)3CC6H4COO]4
Li, Jian-Tong
Yang, Juan
Dai, Jun
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2009, 224 (04): : 582 - 584
[10] The crystal structure of 6,6'-(((2-(dimethylamino) ethyl)azanediyl)bis(methylene))bis(2-chloro4-methyl phenolate-κ4N,N',O,O')-(pyridine2,6-dicarboxylato- N,O,O')-titanium(IV), C27H27Cl2N3O6Ti
Yang, Mingjun
Wang, Canghai
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2023, 238 (05): : 817 - 819

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