Pd-Ni bimetallic nanoparticles supported on ZrO2 as an efficient catalyst for Suzuki-Miyaura reactions

被引：3

作者：

Zhang, Li-jie ^{[1
]}

Yao, Xian ^{[1
]}

Sun, Ying-xin ^{[1
]}

Zhang, Jia-wei ^{[1
]}

Cai, Chun ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Chem Engn, 200 Xiaoling Wei, Nanjing 210094, Jiangsu, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2018年 / 08期

基金：

中国国家自然科学基金;

关键词：

heterogeneous catalysis; alloys; nanochemistry; bimetallic nanoparticles; Suzuki-Miyaura coupling; HETEROGENEOUS CATALYST; COUPLING REACTIONS; REUSABLE CATALYST; PALLADIUM; HYDROGENATION; PERFORMANCE; LIGAND; ARYL;

D O I：

10.3184/174751918X15337409427516

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pd-Ni bimetallic nanoparticles (BMNPs) supported on ZrO2 were prepared by an impregnation-reduction method. The BMNPs showed excellent catalytic performance in Suzuki carbon-carbon cross-coupling reactions and almost quantitative conversion of the substrates was obtained under mild conditions in the absence of ligand. The excellent catalytic performance of the bimetallic catalyst could be a result of the synergistic effect between the two metal components. The catalyst showed outstanding recyclability during the reaction process; no obvious decrease in catalytic performance was observed after five cycles.

引用

页码：419 / 423

页数：5

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