Strain engineering of optical properties in transparent VO2/muscovite heterostructures

被引:23
作者
Chen, Hsaio-Wen [1 ]
Li, Chien-, I [2 ]
Ma, Chun-Hao [2 ]
Chu, Ying-Hao [2 ]
Liu, Hsiang-Lin [1 ]
机构
[1] Natl Taiwan Normal Univ, Dept Phys, Taipei 11677, Taiwan
[2] Natl Chiao Tung Univ, Dept Mat Sci Engn, Hsinchu 30010, Taiwan
关键词
METAL-INSULATOR-TRANSITION; VANADIUM DIOXIDE; LATTICE-DYNAMICS; PHASE-TRANSITION; VO2; SEPARATION; PRESSURE; GRAPHENE; MODES; STATE;
D O I
10.1039/d1cp00642h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transparent VO2/muscovite heterostructures have attracted considerable attention because of their unique chemical and physical properties and potential practical applications. In this paper, we investigated the influence of uniaxial mechanical strain on the optical properties of VO2/muscovite heterostructures through Raman scattering and optical transmittance measurements. Under applied strain, linear shifts in peak positions of Raman-active phonon modes at approximately 340, 309, and 391 cm(-1) were observed. The extracted Gruneisen parameter values were approximately between 0.44 and 0.57. Furthermore, a pronounced strain-induced change in the metal-insulator transition (MIT) temperature was observed, which decreased under compressive strain and increased under tensile strain. The rates of MIT temperature variation reached 4.5 degrees C per % and 7.1 degrees C per % at a wavelength of 1200 nm during heating and cooling processes, respectively. These results demonstrate that the modulation of the optical properties of VO2/muscovite heterostructures is controllable and reversible through strain engineering, opening up new opportunities for applications in flexible and tunable photonic devices.
引用
收藏
页码:8908 / 8915
页数:8
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