Hunig's base a facile and green alternative for C-N bond formation reactions

被引：0

作者：

Taywade, Amol ^{[1
]}

Berad, Baliram ^{[2
]}

机构：

[1] Govt Vidarbha Inst Sci & Humanities, Dept Chem, Amravati 444604, India

[2] Rashtrast Tukadoji Maharaj Nagpur Univ, Dept Chem, Mahatma Jyotiba Phule Educ Campus, Nagpur 440001, Maharashtra, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 2019年 / 58卷 / 08期

关键词：

Green chemistry; solvent free reactions; DIPEA; C-N coupling; B-auto solvent free condition; CROSS-COUPLING REACTIONS; CATALYZED AMINATION; ORGANIC-SYNTHESIS; ARYL HALIDES; EFFICIENT; ARYLATION; LIGANDS; DERIVATIVES; CHEMISTRY; SOLVENTS;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new dimension to Hunig's base i.e. diisopropylethylamine (DIPEA) utilization in the organic reaction has been introduced. Present study projects DIPEA as a green alternative for C-N bond formation reactions. In terms of optimization of yield of C-N coupling reactions, DIPEA exclusively serves as base, catalyst and solvent in mild conditions to fulfill criteria for green reaction methodology.

引用

页码：935 / 943

页数：9

共 46 条

[1]

Ahmed F, 1996, J ORG CHEM, V6, P3849

[2] Green Chemistry: Principles and Practice [J].

Anastas, Paul ;

Eghbali, Nicolas .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :301-312

[3] Origins, current status, and future challenges of green chemistry [J].

Anastas, PT ;

Kirchhoff, MM .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694

[4]

[Anonymous], 1994, Dictionary of natural products

[5] Copper-catalyzed coupling of arylboronic acids and amines [J].

Antilla, JC ;

Buchwald, SL .

ORGANIC LETTERS, 2001, 3 (13) :2077-2079

[6] THE DIRECTED SYNTHESIS OF BIARYL COMPOUNDS - MODERN CONCEPTS AND STRATEGIES [J].

BRINGMANN, G ;

WALTER, R ;

WEIRICH, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (09) :977-991

[7]

CARBERRY JJ, 1966, J IND ENG CHEM, V58, P40

[8] New N- and O-arylations with phenylboronic acids and cupric acetate [J].

Chan, DMT ;

Monaco, KL ;

Wang, RP ;

Winters, MP .

TETRAHEDRON LETTERS, 1998, 39 (19) :2933-2936

[9]

CRAIG PN, 1991, MED CHEM, V8

[10] SYNTHESIS AND CHARACTERIZATION OF POLYANILINE DERIVATIVES - POLY(2-ALKOXYANILINES) AND POLY(2,5-DIALKOXYANILINES) [J].

DAPRANO, G ;

LECLERC, M ;

ZOTTI, G ;

SCHIAVON, G .

CHEMISTRY OF MATERIALS, 1995, 7 (01) :33-42

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