Selective oxidation of naphthalene derivatives with ruthenium catalysts using hydrogen peroxide as terminal oxidant

被引：19

作者：

Shi, Feng

Tse, Man Kin

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29A, D-18059 Rostock, Germany

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 270卷 / 1-2期

关键词：

arene; selective oxidation; hydrogen peroxide; ruthenium; green chemistry;

D O I：

10.1016/j.molcata.2006.12.047

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The selective oxidation of naphthalene and its derivatives to give naphthoquinones has been investigated in detail. The reaction can be carried out effectively in the presence of a catalytic amount of Ru complexes (0.2 mol%) and phase transfer catalysts (PTC) using H2O2 as the terminal oxidant and water as the solvent. The effect of different ruthenium complexes, phase transfer catalysts, and the concentration of hydrogen peroxide were studied. Compared to previous procedures for this type of reactions, acidic solvents and high concentration of hydrogen peroxide are not necessary, which makes the reaction more environmentally friendly. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：68 / 75

页数：8

共 41 条

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