Nonlinear optical properties of two oxazine dyes in aqueous solution and polyacrylamide hydrogel using single beam Z-scan

被引:36
作者
Milanchian, K. [4 ]
Tajalli, H. [2 ,3 ,4 ]
Gilani, A. Ghanadzadeh [1 ,2 ,3 ]
Zakerhamidi, M. S. [2 ]
机构
[1] Univ Guilan, Dept Chem, Fac Sci, Rasht, Iran
[2] Univ Tabriz, Res Inst Appl Phys & Astron, Tabriz, Iran
[3] Univ Tabriz, Photon Excellence Ctr, Tabriz, Iran
[4] Univ Tabriz, Fac Phys, Tabriz, Iran
关键词
Oxazine dyes; Polyacrylamide; Nonlinearity; Z-scan; POLARIZED IR-SPECTROSCOPY; SOLID-STATE; SUPRAMOLECULAR POLYMERIZATION; STRUCTURAL ELUCIDATION; CRYSTAL-STRUCTURE; TEMPERATURE; ADSORPTION; REFRACTION; DIFFUSION; POLYMERS;
D O I
10.1016/j.optmat.2009.05.011
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The nonlinear optical properties of the two oxazine dyes, i.e. oxazine 720 (OX720) and oxazine 750 (OX750), in aqueous solution and in polyacrylamide hydrogel (PAA) matrix were studied by Z-scan technique using CW He-Ne laser at 632.8 nm. All the polymeric and aqueous samples showed a negative nonlinearity and large nonlinear refractive index of the order of 10(-8) cm(2)/W. The concentration-dependent nonlinear refractive index was also investigated. In the case of PAA-dye systems, two types of transit (fast) and steady state (slow) nonlinear effects were observed. It is believed that these effects are due to the thermo-optical induced refractive index gradient and a concentration gradient induced by a temperature gradient present in a medium. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:12 / 17
页数:6
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