Kinetics of Ag-rich precipitates formation in Cu-Al-Ag alloys

被引:15
作者
Adorno, AT [1 ]
Guerreiro, MR [1 ]
Silva, RAG [1 ]
机构
[1] UNESP, Inst Quim, Dept Quim Fis, BR-14801970 Araraquara, SP, Brazil
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2004年 / 374卷 / 1-2期
关键词
microhardness; kinetics; diffusion; nucleation; Cu-Al-Ag alloys;
D O I
10.1016/j.msea.2004.02.006
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The kinetics of Ag-rich precipitates formation in the Cu-2 wt.% Al alloy with additions of 2, 4, 6, 8, 10 and 12 wt.% Ag was studied using microhardness changes with temperature and time, differential scanning calorimetry (DSC), differential thermal analysis (DTA), scanning electron microscopy (SEM), optical microscopy (OM), energy dispersive X-ray analysis (EDX) and X-ray diffractometry (XRD). The results indicated that an increase in the Ag content decreases the activation energy for Ag-rich precipitates formation, and that it is possible to estimate the values of the diffusion and nucleation activation energies for the Ag precipitates. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:170 / 176
页数:7
相关论文
共 10 条
[1]   Aging kinetics in the Cu-8 wt.% Al alloy with Ag additions [J].
Adorno, AT ;
Guerreiro, MR ;
Silva, RAG .
JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 354 (1-2) :165-170
[2]   Determination of the activation energies for precipitates nucleation and silver diffusion in the Cu-2wt.%Al alloy with silver additions. [J].
Adorno, AT ;
Guerreiro, MR ;
Benedetti, AV .
ECLETICA QUIMICA, 2001, 26 :99-109
[3]   Influence of silver additions on the thermal behavior of the Cu-8 mass% Al alloy [J].
Adorno, AT ;
Guerreiro, MR ;
Ribeiro, CA ;
Guerreiro, CTR .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2001, 64 (03) :1141-1146
[4]   Effect of segregation on the shape of grain boundary diffusion profiles Experimental study of the Cu-Ag system [J].
Bernardini, J ;
Tokei, Z ;
Beke, DL .
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1996, 73 (01) :237-247
[5]   Age hardening in beryllium-aluminum-silver alloys [J].
Carter, DH ;
McGeorge, AC ;
Jacobson, LA ;
Stanek, PW .
ACTA MATERIALIA, 1996, 44 (11) :4311-4315
[6]   RECRYSTALLIZATION IN INTERNALLY OXIDIZED CU-AG-AL ALLOYS [J].
CHOPRA, OK ;
NIESSEN, P .
JOURNAL OF MATERIALS SCIENCE, 1974, 9 (02) :279-288
[7]  
Christian J. W, 1975, THEORY TRANSFORMATIO, p[15, 525]
[8]  
Draper N. R., 1966, APPL REGRESSION ANAL
[9]  
GULYAEV A, 1980, PHYS METALL, V2, P282
[10]   Energetic and kinetic evaluations in a quasi-binary Cu-1 at. % Co2Si alloy [J].
Varschavsky, A ;
Donoso, E .
MATERIALS LETTERS, 2003, 57 (07) :1266-1271