A Rapid Aqueous Fluoride Ion Sensor with Dual Output Modes

被引:531
作者
Hu, Rui [1 ]
Feng, Jiao [1 ]
Hu, Dehui [1 ]
Wang, Shuangqing [1 ]
Li, Shayu [1 ]
Li, Yi [2 ]
Yang, Guoqiang [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
fluorescent probes; fluorides; luminescence; sensors; silicon; SELECTIVE ELECTRODE POTENTIOMETRY; INTRAMOLECULAR PROTON-TRANSFER; INDUCED EMISSION ENHANCEMENT; CAPILLARY-ELECTROPHORESIS; ORGANIC SYSTEMS; ENERGY TRANSFER; FLUORESCENT; ANION; CHEMOSENSOR; WATER;
D O I
10.1002/anie.201000790
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) The color purple: A siloxy-functionalized benzamide (see picture) is a highly efficient fluoride ion sensor in water. The sensor, which is activated when the O-Si bond is cleaved by fluoride ions, provides two independent modes for signal recognition. In colorimetric mode, the fluoride ion concentration is transformed into a fluorescence signal that can be observed directly with the naked eye. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, weinheim.
引用
收藏
页码:4915 / 4918
页数:4
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