Plasma treatment of multiwall carbon nanotubes for dispersion improvement in water

被引:63
作者
Chen, Changlun [1 ,2 ]
Ogino, Akihisa [1 ]
Wang, Xiangke [2 ]
Nagatsu, Masaaki [1 ]
机构
[1] Shizuoka Univ, Grad Sch Sci & Technol, Hamamatsu, Shizuoka 4328561, Japan
[2] Chinese Acad Sci, Inst Plasma Phys, Key Lab Novel Thin Film Solar Cell, Hefei 230031, Peoples R China
关键词
carbon nanotubes; field emission electron microscopy; plasma materials processing; Raman spectra; scanning electron microscopy; surface morphology; surface treatment; transmission electron microscopy; X-ray photoelectron spectra; FUNCTIONAL-GROUPS; OZONE OXIDATION; OXYGEN; FILMS;
D O I
10.1063/1.3377007
中图分类号
O59 [应用物理学];
学科分类号
摘要
Microwave excited Ar/H(2)O surface-wave plasma was used to treat multiwall carbon nanotubes (MWCNTs) to modify their surface characteristics and thus improve their dispersion capability in water. Changes in the atom composition and structure properties of MWCNTs were analyzed using x-ray photoelectron spectroscopy and Raman spectroscopy, and the surface morphology of MWCNTs was observed by field emission scanning electron microscopy and scanning transmission electron microscopy. The results indicated that Ar/H(2)O plasma treatment greatly enhanced the content of oxygen, and modified surface microstructure properties. The integrity of nanotube patterns, however, was not damaged.
引用
收藏
页数:3
相关论文
共 16 条
[1]   Work functions and surface functional groups of multiwall carbon nanotubes [J].
Ago, H ;
Kugler, T ;
Cacialli, F ;
Salaneck, WR ;
Shaffer, MSP ;
Windle, AH ;
Friend, RH .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (38) :8116-8121
[2]   OPENING CARBON NANOTUBES WITH OXYGEN AND IMPLICATIONS FOR FILLING [J].
AJAYAN, PM ;
EBBESEN, TW ;
ICHIHASHI, T ;
IIJIMA, S ;
TANIGAKI, K ;
HIURA, H .
NATURE, 1993, 362 (6420) :522-525
[3]  
Hamon MA, 1999, ADV MATER, V11, P834, DOI 10.1002/(SICI)1521-4095(199907)11:10<834::AID-ADMA834>3.0.CO
[4]  
2-R
[5]   Ar, O2, CHF3, and SF6 plasma treatments of screen-printed carbon nanotube films for electrode applications [J].
Hou, Zhonyu ;
Cai, Binchu ;
Liu, Hai ;
Xu, Dong .
CARBON, 2008, 46 (03) :405-413
[6]  
IIJIMA S, 1991, NATURE, V35, P456
[7]   Enhancement of microplasma-based water-solubilization of single-walled carbon nanotubes using gas bubbling in water [J].
Imasaka, Kiminobu ;
Kato, Yuki ;
Suehiro, Junya .
NANOTECHNOLOGY, 2007, 18 (33)
[8]   Oxygen-containing functional groups on single-wall carbon nanotubes: NEXAFS and vibrational spectroscopic studies [J].
Kuznetsova, A ;
Popova, I ;
Yates, JT ;
Bronikowski, MJ ;
Huffman, CB ;
Liu, J ;
Smalley, RE ;
Hwu, HH ;
Chen, JGG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (43) :10699-10704
[9]   Effects of substitutional B on oxidation of carbon nanotubes in air and oxygen plasma [J].
Lee, YJ ;
Kim, HH ;
Hatori, H .
CARBON, 2004, 42 (5-6) :1053-1056
[10]   Infrared spectral evidence for the etching of carbon nanotubes: Ozone oxidation at 298 K [J].
Mawhinney, DB ;
Naumenko, V ;
Kuznetsova, A ;
Yates, JT ;
Liu, J ;
Smalley, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (10) :2383-2384