Heterocycles Incorporating a Pentacoordinated, Hypervalent Phosphorus Atom

被引：6
作者：
Krasowska, Dorota [1 ]
Pokora-Sobczak, Patrycja [1 ]
Jasiak, Aleksandra [1 ]
Drabowicz, Jozef [1 ,2 ]
机构：
[1] Polish Acad Sci, Lodz, Poland
[2] Jan Dlugosz Univ, Czestochowa, Poland
来源：
ADVANCES IN HETEROCYCLIC CHEMISTRY, VOL 124 | 2018年 / 124卷
关键词：
Chirality; Heterocycles; Hypervalency; Phosphoranes; Pseudorotation; H OXIDATIVE ADDITION; MOLECULAR-STRUCTURE; 1ST ISOLATION; DERIVATIVES; BEARING; SPIROPHOSPHORANE; CHEMISTRY; CRYSTAL; HYDRIDOPHOSPHORANES; TRIALKYLPHOSPHITES;
D O I：
10.1016/bs.aihch.2017.06.002
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This chapter presents the synthesis of heterocycles with a hypervalent, pentacoordinated phosphorus atom. It is divided into two sections. The first is devoted to the preparation of pentavalent, pentacoordinated, hypervalent monocyclic phosphoranes, and their selected interconversions. The second section, concerning bicyclic heterocycles, describes the synthesis and reactivity of all kinds of bicyclic phosphoranes. The phenomenon of chirality for this group of organophosphorus derivatives is also briefly discussed.
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页码：175 / 231
页数：57
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