Relative Permittivity of Monocomponent and Binary Solutions of N2O5 in Liquid CO2 and Their Activity in Nitration of Cellulose

被引：4
作者：
Guskov, A. A. [1 ]
Kuchurov, I. V. [1 ]
Zlotin, S. G. [1 ]
机构：
[1] Russian Acad Sci, Zelinskii Inst Organ Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B | 2015年 / 9卷 / 08期
关键词：
carbon dioxide; cellulose; nitrocellulose; nitration; relative permittivity; dinitrogen pentoxide; nitric acid; supercritical drying; CARBON-DIOXIDE; HEAT-CAPACITIES; MIXTURES;
D O I：
10.1134/S1990793115080059
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Static relative permittivity of liquid carbon dioxide solutions of dinitrogen pentoxide and its mixtures with nitric, acetic or trifluoroacetic acids is measured. The procedure for nitration of cellulose acquired from various natural noncotton sources (wood, linen, hemp) by mixtures of dinitrogen pentoxide and 100% nitric acid in a carbon dioxide medium is developed. A supercritical drying technique is implemented for dehydration of wet nitrocellulose.
引用
收藏
页码：1130 / 1136
页数：7
相关论文
共 22 条
  • [1] Agrawal J.P., 2007, Organic Chemistry of Explosives
  • [2] AUDRIETH LF, 1950, INORGANIC SYNTHESES, V3
  • [3] Bludova O. S., 1984, ZH PRIKL KHIM, P603
  • [4] Drying of foods using supercritical carbon dioxide - Investigations with carrot
    Brown, Z. K.
    Fryer, P. J.
    Norton, I. T.
    Bakalis, S.
    Bridson, R. H.
    [J]. INNOVATIVE FOOD SCIENCE & EMERGING TECHNOLOGIES, 2008, 9 (03) : 280 - 289
  • [5] Farncomb R. E., 2001, US Patent, Patent No. 6177033
  • [6] Galitskaya I. M., 1990, METHODS PRODUCTION A
  • [7] HEAT-CAPACITIES AND DENSITIES OF MIXTURES OF VERY POLAR SUBSTANCES .2. MIXTURES CONTAINING N,N-DIMETHYLFORMAMIDE
    GROLIER, JPE
    ROUXDESGRANGES, G
    BERKANE, M
    JIMENEZ, E
    WILHELM, E
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 1993, 25 (01) : 41 - 50
  • [8] HUGHES E D, 1946, Nature, V158, P448, DOI 10.1038/158448c0
  • [9] VOLUMES AND HEAT-CAPACITIES OF BINARY NONAQUEOUS MIXTURES .2. THE SYSTEMS ACETONITRILE N,N-DIMETHYLFORMAMIDE AND ACETONITRILE HEXAMETHYLPHOSPHORIC TRIAMIDE
    KOLKER, AM
    KULIKOV, MV
    KRESTOV, AG
    [J]. THERMOCHIMICA ACTA, 1992, 211 : 73 - 84
  • [10] Atomic force microscopy of mammalian urothelial surface
    Kreplak, Laurent
    Wang, Huaibin
    Aebi, Ueli
    Kong, Xiang-Peng
    [J]. JOURNAL OF MOLECULAR BIOLOGY, 2007, 374 (02) : 365 - 373
123