Copolymerization of divinyl monomers with maleic and fumaric acid derivatives

被引：0
|
作者：
Tsarik, LY [1 ]
Novikov, ON [1 ]
Magdinets, VV [1 ]
机构：
[1] Irkutsk State Univ, Dept Chem, Irkutsk 664033, Russia
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1998年 / 36卷 / 03期
关键词：
copolymerization; divinyl monomers; diethyl fumarate; maleic anhydride; divinylbenzene;
D O I：
10.1002/(SICI)1099-0518(199802)36:3<371::AID-POLA1>3.0.CO;2-V
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The process of formation of reticular copolymer molecular structures produced in free radical copolymerization of divinyl monomers ( divinyl ethers of diethylene glycol and hydroquinone, divinyl sulfide, p-divinylbenzene, etc.) with maleic and fumaric acid derivatives is studied. The basic factor that determines the features of molecular and network structures of copolymers is reactivity of the divinyl monomer in copolymerization with monovinyl monomer. The network of copolymers of maleic anhydride with the divinyl ether of hydroquinone is formed out of oligomer microgels. Divinyl sulfide in copolymerization with maleic acid is disposed to cyclocopolymerization; also crosslinking reactions occur. Formation of a network structure of copolymers of divinylbenzene with maleic and fumaric acid derivatives is shown to proceed via an alternating copolymerization mechanism. (C) 1998 John Wiley & Sons, Inc.
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页码：371 / 378
页数：8
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