Modular assembly of two-dimensional metal-organic coordination networks at a metal surface

被引：253
作者：
Dmitriev, A
Spillmann, H
Lin, N
Barth, JV [1 ]
Kern, K
机构：
[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
[2] Ecole Polytech Fed Lausanne, Inst Phys Nanostruct, CH-1015 Lausanne, Switzerland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 23期
关键词：
coordination compounds; iron; nanomaterials; scanning tunneling microscopy; vacuum deposition;
D O I：
10.1002/anie.200250610
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Impressive iron networks: Two-dimensional metal-organic coordination networks have been prepared by the vacuum deposition of organic polytopic linkers and metal atoms on a copper surface. This unprecedented technique enabled the modular assembly of open Fe-carboxylate grids (see image, Fe atoms in green) that possess regularly spaced, identically shaped cavities. The structure and composition of the networks can be tuned by controlling the deposition parameters.
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页码：2670 / 2673
页数：4
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