Nitrocyclopropanes : synthesis and properties

被引：25

作者：

Averina, E. B. ^{[1
]}

Yashin, N. V. ^{[1
]}

Kuznetsova, T. S. ^{[1
]}

Zefirov, N. S. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2009年 / 78卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

ELECTRONICALLY EFFECTIVE CARBONYL; STRAINED-RING COMPOUNDS; (1; ALPHA; 5; 6; CYCLOPROPANE DERIVATIVES; CONJUGATE ADDITION; 1ST SYNTHESIS; NITRO-GROUP; ASYMMETRIC CYCLOPROPANATION; CATALYTIC CYCLOPROPANATION; ACTIVATED CYCLOPROPANES;

D O I：

10.1070/RC2009v078n10ABEH004050

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Present knowledge on the methods of synthesis, properties and transformations of nitro- and dinitrocyclopropanes is generalized and described systematically. The main attention is given to the methods of stereoselective cyclopropanation, new approaches to the synthesis of natural compounds and their synthetic analogues with diverse biological activity, in particular, the nitrocyclopropane-based synthesis of aminocyclopropanecarboxylic acids as well as to the construction of energetic compounds. The bibliography includes 112 references.

引用

页码：887 / 902

页数：16

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