Divergent Synthesis of Carbo- and Heterocycles via Gold-Catalyzed Reactions

被引：161

作者：

Wei, Yin ^{[1
]}

Shi, Min ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China

来源：

ACS CATALYSIS | 2016年 / 6卷 / 04期

基金：

中国国家自然科学基金;

关键词：

gold catalysis; carborycles; heterocycles; cycloisomerization; cycloaddition; PALLADIUM-MEDIATED SYNTHESIS; COUPLING REACTIONS; TERMINAL ALKYNES; C-C; GOLD(I)-CATALYZED CYCLOISOMERIZATION; INTERMOLECULAR 2+2; DUAL-ACTIVATION; SELECTIVITY; COPPER; CYCLIZATIONS;

D O I：

10.1021/acscatal.6b00048

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The latest advances in the field of gold catalyzed divergent synthesis of carbo- and heterocycles are highlighted in this Perspective. These gold-catalyzed reactions, which can provide structurally novel carbo- and heterocycles, were achieved with good product selectivities, through subtle choice of substrates, catalysts, ligands, and counterions. The related reaction mechanisms are also discussed.

引用

收藏

页码：2515 / 2524

页数：10

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