Probing the local structure of crystalline ZITO: In2-2xSnxZnxO3 (x ≤ 0.4)

被引：26

作者：

Hoel, Cathleen A. ^{[1
]}

Gaillard, Jean-Francois ^{[2
]}

Poeppelmeier, Kenneth R. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Civil & Environm Engn, Evanston, IL 60208 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2010年 / 183卷 / 04期

基金：

美国国家科学基金会;

关键词：

Indium oxide; Cosubstitution; Solid solution; EXAFS; Transparent conducting oxide; X-ray absorption spectroscopy; RAY-ABSORPTION-SPECTROSCOPY; TRANSPARENT CONDUCTING OXIDES; IN2O3; DIFFRACTION; IFEFFIT; XAFS; BULK; FEFF;

D O I：

10.1016/j.jssc.2010.01.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The local structure of In2O3 cosubstituted with Zn and Sn (In2-2xSnxZnxO3, x <= 0.4 or ZITO) was determined by extended X-ray absorption fine structure (EXAFS) for x=0.1, 0.2, 0.3 and 0.4. The host bixbyite In2O3 structure is maintained up to the enhanced substitution limit (x=0.4). The EXAFS spectra are consistent with random substitution of In by the smaller Zn and Sn cations, a result that is consistent with the "good-to-excellent" conductivities reported for ZITO. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：761 / 768

页数：8

共 26 条

[1] RUTILE-TYPE COMPOUNDS .4. SIO2, GEO2 AND A COMPARISON WITH OTHER RUTILE-TYPE STRUCTURES [J].

BAUR, WH ;

KHAN, AA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (NOV15) :2133-&

[2] Basic materials physics of transparent conducting oxides [J].

Edwards, PP ;

Porch, A ;

Jones, MO ;

Morgan, DV ;

Perks, RM .

DALTON TRANSACTIONS, 2004, (19) :2995-3002

[3] Transparent conducting oxides for photovoltaics [J].

Fortunato, Elvira ;

Ginley, David ;

Hosono, Hideo ;

Paine, David C. .

MRS BULLETIN, 2007, 32 (03) :242-247

[4] TRANSPARENT HEAT-REFLECTING COATINGS BASED ON HIGHLY DOPED SEMICONDUCTORS [J].

FRANK, G ;

KAUER, E ;

KOSTLIN, H .

THIN SOLID FILMS, 1981, 77 (1-3) :107-117

[5] Defect structure studies of bulk and nano-indium-tin oxide [J].

González, GB ;

Mason, TO ;

Quintana, JP ;

Warschkow, O ;

Ellis, DE ;

Hwang, JH ;

Hodges, JP ;

Jorgensen, JD .

JOURNAL OF APPLIED PHYSICS, 2004, 96 (07) :3912-3920

[6] Carrier generation and inherent off-stoichiometry in Zn, Sn codoped indium oxide (ZITO) bulk and thin-film specimens [J].

Harvey, Steven P. ;

Mason, Thomas O. ;

Buchholz, D. Bruce ;

Chang, Robert P. H. ;

Korber, Christoph ;

Klein, Andreas .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2008, 91 (02) :467-472

[7] Subsolidus Phase Relationships in the ZnO-In2O3-SnO2 System [J].

Harvey, Steven P. ;

Poeppelmeier, Kenneth R. ;

Mason, Thomas O. .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2008, 91 (11) :3683-3689

[8]

Kelly S. D., 2008, METHODS SOIL ANAL 5, V5

[9] REFINEMENT OF CRYSTAL STRUCTURE OF IN2O3 AT 2 WAVELENGTHS [J].

MAREZIO, M .

ACTA CRYSTALLOGRAPHICA, 1966, 20 :723-&

[10] Point defects and related properties of highly co-doped bixbyite In2O3 [J].

Mason, TO ;

González, GB ;

Hwang, JH ;

Kammler, DR .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (11) :2183-2189

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