A macrocyclic triolefinic palladium(0) complex covalently anchored to a mesostructured silica as active and reusable catalyst for Suzuki cross-coupling reactions

被引:39
作者
Blanco, B
Mehdi, A [1 ]
Moreno-Mañas, M
Pleixats, R
Reyé, C
机构
[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Cerdanyola Del Valles, Barcelona, Spain
[2] Univ Montpellier 2, UMR 5637 CNRS, Lab Chim Mol & Org Solide, F-34095 Montpellier 5, France
关键词
macrocyclic triolefinic complex; recoverable palladium catalyst; mesostructured silica; hybrid material; Suzuki cross-coupling;
D O I
10.1016/j.tetlet.2004.10.007
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A mesoporous hybrid material containing a 15-membered triazamacrocyclic triolefinic palladium(0) complex was prepared and successfully tested as a reusable heterogeneous catalyst for Suzuki cross-couplings in organic solvents. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8789 / 8791
页数:3
相关论文
共 28 条
[1]   Oxime carbapalladacycle covalently anchored to high surface area inorganic supports or polymers as heterogeneous green catalysts for the Suzuki reaction in water [J].
Baleizao, C ;
Corma, A ;
García, H ;
Leyva, A .
JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (02) :439-446
[2]   An oxime-carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water [J].
Baleizao, C ;
Corma, A ;
García, H ;
Leyva, A .
CHEMICAL COMMUNICATIONS, 2003, (05) :606-607
[3]   Silica-supported imine palladacycles - recyclable catalysts for the Suzuki reaction? [J].
Bedford, RB ;
Cazin, CSJ ;
Hursthouse, MB ;
Light, ME ;
Pike, KJ ;
Wimperis, S .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 633 (1-2) :173-181
[4]  
Biffis A, 2001, EUR J INORG CHEM, P1131
[5]   The [(E,E,E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,18,13-triene]Pd(0) complex in the hydroarylation of alkynes in ionic liquids.: An approach to quinolines [J].
Cacchi, S ;
Fabrizi, G ;
Goggiamani, A ;
Moreno-Mañas, M ;
Vallribera, A .
TETRAHEDRON LETTERS, 2002, 43 (32) :5537-5540
[6]  
Cerezo S, 2001, EUR J ORG CHEM, V2001, P329
[7]   Palladium(0)-catalyzed allylation of highly acidic and non-nucleophilic arenesulfonamides, sulfamide, and cyanamide.: II.: Formation of medium and large heterocycles [J].
Cerezo, S ;
Cortés, J ;
López-Romero, JM ;
Moreno-Mañas, M ;
Parella, T ;
Pleixats, R ;
Roglans, A .
TETRAHEDRON, 1998, 54 (49) :14885-14904
[8]   Study of the accessibility of phosphorus centres incorporated within ordered mesoporous organic-inorganic hybrid materials [J].
Corriu, RJP ;
Hoarau, C ;
Mehdi, A ;
Reyé, C .
CHEMICAL COMMUNICATIONS, 2000, (01) :71-72
[9]   Direct synthesis of functionalized mesoporous silica by non-ionic assembly routes.: Quantitative chemical transformations within the materials leading to strongly chelated transition metal ions [J].
Corriu, RJP ;
Mehdi, A ;
Reyé, C ;
Thieuleux, C .
CHEMISTRY OF MATERIALS, 2004, 16 (01) :159-166
[10]   Ordered SBA-15 mesoporous silica containing phosphonic acid groups prepared by a direct synthetic approach [J].
Corriu, RJP ;
Datas, L ;
Guari, Y ;
Mehdi, A ;
Reyé, C ;
Thieuleux, C .
CHEMICAL COMMUNICATIONS, 2001, (08) :763-764