Impact of the functional group in the polyanion of single lithium-ion conducting polymer electrolytes on the stability of lithium metal electrodes

被引：67
|
作者：
Ma, Qiang [1 ]
Xia, Yu [1 ]
Feng, Wenfang [1 ]
Nie, Jin [1 ]
Hu, Yong-Sheng [2 ]
Li, Hong [2 ]
Huang, Xuejie [2 ]
Chen, Liquan [2 ]
Armand, Michel [3 ]
Zhou, Zhibin [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Minist Educ, Key Lab Mat Chem Energy Convers & Storage, 1037 Luoyu Rd, Wuhan 430074, Peoples R China
[2] Chinese Acad Sci, Key Lab Renewable Energy, Beijing Key Lab New Energy Mat & Devices, Beijing Natl Lab Condensed Matter Phys,Inst Phys, Beijing 100190, Peoples R China
[3] CIC Energigune, Alava Technol Pk, Minano 4801510, Alava, Spain
来源：
RSC ADVANCES | 2016年 / 6卷 / 39期
基金：
中国国家自然科学基金;
关键词：
DELOCALIZED POLYANION; BATTERIES; PERFORMANCE; COPOLYMERS; COMPLEXES; SALTS;
D O I：
10.1039/c6ra01387b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel single lithium-ion (Li-ion) conducting polymer electrolyte composed of lithium poly[(4-styrenesulfonyl)(fluorosulfonyl) imide] (LiPSFSI) and poly(ethylene oxide) (PEO) exhibits a high Li-ion transference number (t(Li)(+) = 0.90) and sufficient electrochemical stability for use in Li batteries. The ionic conductivities of the LiPSFSI/PEO blended polymer electrolytes are higher than those of the lithium poly(4-styrenesulfonate) (LiPSS)/PEO electrolyte and are comparable to those of the lithium poly[(4styrenesulfonyl)( trifluoromethanesulfonyl) imide] (LiPSTFSI)/PEO electrolyte in the temperature range of 25-90 degrees C. More importantly, the complex of LiPSFSI/PEO exhibits excellent interfacial compatibility with the Li metal electrode compared to both those of the LiPSS/PEO and LiPSTFSI/PEO electrolytes.
引用
收藏
页码：32454 / 32461
页数：8
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