Design of dispersant for highly concentrated one-dimensional Nb2Se9 inorganic molecular chains from bulk crystal

被引:6
作者
Chae, Sudong [1 ]
Siddiqa, Akhtar J. [1 ]
Oh, Seungbae [1 ]
Kim, Bum Jun [2 ]
Choi, Kyung Hwan [2 ]
Yu, Hak Ki [3 ,4 ]
Choi, Jae-Young [1 ,2 ]
机构
[1] Sungkyunkwan Univ, Sch Adv Mat Sci & Engn, Suwon 16419, South Korea
[2] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol SAINT, Suwon 16419, South Korea
[3] Ajou Univ, Dept Mat Sci & Engn, Suwon 16499, South Korea
[4] Ajou Univ, Dept Energy Syst Res, Suwon 16499, South Korea
基金
新加坡国家研究基金会;
关键词
MO6S9-XIX NANOWIRES; CARBON NANOTUBES; SOLAR-CELLS; EXFOLIATION; ACID;
D O I
10.1038/s41598-019-51210-z
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We determined the optimum dispersant to separate bulk Nb2Se9 material into 1D chain units. The Nb2Se9, which had a negative zeta potential (-43.3 mV), showed acidic characteristics and strongly bonded with the amine head of octadecyl amine through a charge transfer (from the amine to Se atoms) reaction. The steric hindrance of the octadecyl tail resulted in excellent dispersion of Nb2Se9 (down to nanometre-sized mono-chains).
引用
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页数:6
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