Synthesis and Structure-Activity Relationship of a WO3 Catalyst for the Total Oxidation of BTX

被引：59

作者：

Balzer, Rosana ^{[1
]}

Drago, Valderez ^{[2
]}

Schreiner, Wido H. ^{[3
]}

Probst, Luiz F. D. ^{[1
]}

机构：

[1] Univ Fed Santa Catarina, Dept Chem, BR-88040900 Florianopolis, SC, Brazil

[2] Univ Fed Santa Catarina, Dept Phys, BR-88040900 Florianopolis, SC, Brazil

[3] Univ Fed Parana UFPR, Dept Phys, BR-81531970 Curitiba, PR, Brazil

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2014年 / 25卷 / 11期

关键词：

tungsten oxide; catalytic oxidation; BTX; ACTIVATED CARBON; N-HEXANE; OXIDE; COMBUSTION; TOLUENE; ISOMERIZATION; MICROSPHERES; HYDROCARBONS; XEROGEL; FILMS;

D O I：

10.5935/0103-5053.20140187

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study we prepared a WO3-based catalyst to investigate its catalytic activity in the total oxidation of the volatile organic compounds known as benzene, toluene and xylene (BTX). For a range of low temperatures (50-450 degrees C) the only reaction products were CO2 and H2O. The results for the catalyst characterization suggested that the high catalytic activity could be attributed to the effects of a strong metal interaction, which is possibly originated from the small lattice parameter difference between the (111), (020) and (002) lattice planes and the presence of W4+, W5+ and W6+ species on the surface of the catalyst which react with active oxygen species.

引用

页码：2026 / 2031

页数：6

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