Tetraphenylbismuth 2,4-dimethylbenzenesulfonate: Synthesis and structure

被引：4

作者：

Sharutin, VV

Egorova, IV

Ivanenko, TK

Sharutina, OK

Pavlushkina, II

Gerasimenko, AV

机构：

[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia

[2] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

Physical Chemistry; Bond Length; Diffraction Analysis; Bromine; Bipyramidal;

D O I：

10.1023/A:1023619616897

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetraphenylbismuth 2,4-dimethylbenzenesulfonate was synthesized by reacting pentaphenylbismuth or bromine with diphenylbismuth 2,4-dimethylbenzenesulfonate and its structure was established using X-ray diffraction analysis. The Bi atom has a distorted trigonal bipyramidal coordination. The Bi-C bond lengths are equal to 2.199(4)-2.227(4) Angstrom; the Bi-O distance and axial CBiO angle are equal to 2.665(3)degrees and 174.2(1)degrees, respectively.

引用

页码：317 / 321

页数：5

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