Enantiomeric separation of epinephrine and salbutamol by micellar electrokinetic chromatography using β-cyclodextrin as chiral additive

被引：0
|
作者：
Zheng, YP [1 ]
Mo, JY
机构：
[1] Beijing Jiaotong Univ, Sch Sci, Beijing 10044, Peoples R China
[2] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2004年 / 15卷 / 10期
关键词：
micellar electrokinetic chromatography; electrochemical detection; enantiomer separation; epinephrine; salbutamol;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Enantiomeric separation of epinephrine and salbutamol was investigated by micellar electrokinetic chromatography employing beta-cyclodextrin as chiral additive in ammonium chloride-ammonia solution. The analytes were detected by electrochemistry using gold microelectrode at +0.65 V versus SCE reference electrode. The effects of detection potential, concentration of beta-cyclodextrin, concentration of sodium dodecyl sulfate, pH value of electrolyte and applied voltage were discussed.
引用
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页码：1209 / 1211
页数：3
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