Outer-sphere anion-anion charge transfer in a solid hexacyanoferrate

被引:0
|
作者
Gorel'skii, SI
Kim, TG
Klimova, TP
Kotov, VY [1 ]
Lokshin, BV
Perfil'ev, YD
Sherbak, TI
Tsirlina, GA
机构
[1] Russian Acad Sci, Higher Chem Coll, Moscow 125047, Russia
[2] York Univ, Dept Chem, Toronto, ON M3J 1P3, Canada
[3] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia
[4] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A solid solution based on Cs2Mg[Fe(CN)(6)] containing both [Fe(CN)(6)](4-) and [Fe(CN)(6)](3-) ions exhibits a green colour associated with electronic absorption spectra bands due to the outer-sphere charge transfer between complex anions.
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页码:86 / 87
页数:2
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