Transport and magneto-transport study on some conducting polyanilines

被引:4
作者
Angappane, S
Srinivasan, D
Rangarajan, G [1 ]
Prasad, V
Subramanyam, SV
Wessling, B
机构
[1] Indian Inst Technol, Dept Phys, Chennai 600036, Tamil Nadu, India
[2] Indian Inst Sci, Dept Phys, Bangalore 560012, Karnataka, India
[3] Ormecon Chem GmbH & Co, D-22949 Ammersbek, Germany
来源
PHYSICA B | 2000年 / 284卷
关键词
conducting polymers; disordered metals; PAni; PAni-PMMA; polyaniline;
D O I
10.1016/S0921-4526(99)02949-X
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The room temperature electrical conductivities of pristine polyaniline (PAni), its blend with PMMA (polymethylmethacrylate) in the ratio 2:3 and PAni extracted from the blend were found to be 18, 29 and 73 S/cm, respectively. The temperature dependence of conductivity was also found to differ markedly: for the extract and the blends it is weakly temperature dependent over the interval 300-1.2 K. Reduced activation energy versus temperature plots showed that, while the unblended PAni is on the insulating side of the M-I transition, the blends and the extracted PAni are on the metallic side. The magneto-conductivity (MC) of the extracted PAni is discussed in terms of localization and Coulomb interaction effects. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1982 / 1983
页数:2
相关论文
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