Reactions of both aluminum hydride cluster anions and boron aluminum hydride cluster anions with oxygen: Anionic products

被引：7

作者：

Zhang, Xinxing ^{[1
]}

Wang, Haopeng ^{[1
]}

Gantefoer, Gerd ^{[2
]}

Eichhorn, Bryan W. ^{[3
]}

Bowen, Kit ^{[1
]}

机构：

[1] Johns Hopkins Univ, Dept Chem, Charles & 34Th St, Baltimore, MD 21218 USA

[2] Univ Konstanz, Fac Phys, D-78457 Constance, Germany

[3] Univ Maryland, Dept Chem, College Pk, MD 20742 USA

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2016年 / 404卷

关键词：

Mass spectrometry; Anions; Clusters; PHOTOELECTRON-SPECTROSCOPY; EXPLOSIVE OXIDATION; ELEVATED PRESSURE; PENTABORANE; COMBUSTION; DIBORANE; BEHAVIOR; DENSITY; TEMPERATURE; EXCHANGE;

D O I：

10.1016/j.ijms.2016.04.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The anionic products of reactions between aluminum hydride cluster anions and oxygen and between boron aluminum hydride cluster anions and oxygen were identified by mass spectrometry. While aluminum oxide anions dominated the products of both reactions, low intensities of hydrogen-containing aluminum oxide product anions were also observed in both cases. Surprisingly, in the reactions between boron aluminum hydride cluster anions and oxygen, there was scant evidence for boron-containing anionic products. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：24 / 28

页数：5

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