Recent Methodologies That Exploit C-C Single-Bond Cleavage of Strained Ring Systems by Transition Metal Complexes

被引：791

作者：

Fumagalli, Gabriele ^{[1
]}

Stanton, Steven ^{[1
]}

Bower, John F. ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL REVIEWS | 2017年 / 117卷 / 13期

基金：

欧洲研究理事会; 英国工程与自然科学研究理事会;

关键词：

CARBON-CARBON BOND; 3+2 INTRAMOLECULAR CYCLOADDITION; NICKEL-CATALYZED CYCLOADDITION; INTERMOLECULAR ALKYNE INSERTION; AMINO-SUBSTITUTED CYCLOPROPANES; ENANTIOSELECTIVE CONSTRUCTION; (3+2)+2 CARBOCYCLIZATION; OXIDATIVE CYCLIZATION; COUPLING REACTIONS; SITE-SELECTIVITY;

D O I：

10.1021/acs.chemrev.6b00599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this review, synthetic and mechanistic aspects of key methodologies that exploit C-C single-bond cleavage of strained ring systems are highlighted. The focus is on transition-metal-catalyzed processes that are triggered by C-C bond activation and beta-carbon elimination, with the review concentrating on developments from mid-2009 to mid-2016.

引用

页码：9404 / 9432

页数：29

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