Oxidative esterification of alcohols and aldehydes using supported iron oxide nanoparticle catalysts

被引：26

作者：

Rajabi, Fatemeh ^{[1
]}

Arancon, Rick A. D. ^{[2
]}

Luque, Rafael ^{[2
]}

机构：

[1] Payame Noor Univ, Dept Sci, Tehran, Iran

[2] Univ Cordoba, Dept Quim Organ, E-14014 Cordoba, Spain

来源：

CATALYSIS COMMUNICATIONS | 2015年 / 59卷

关键词：

Supported iron oxide nanopartides; Oxidative esterification; Room temperature catalysis; SOYBEAN OIL; ESTERS; TRANSESTERIFICATION; TRANSFORMATION; BIODIESEL;

D O I：

10.1016/j.catcom.2014.09.022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis of esters has become an important industrial methodology over the past years because of the role that they serve in the chemical industry. In this study, we present the use of a novel catalyst for the direct conversion of aldehydes into esters. The yields obtained using supported iron oxide nanoparticle catalysts (FeNP) are very high (>90%). The catalyst is also shown to be very stable as shown by the recyclability study (up to 11 times). (C) 2014 Published by Elsevier B.V.

引用

收藏

页码：101 / 103

页数：3

相关论文

共 21 条

[1] Versatile low-loaded mechanochemically synthesized supported iron oxide nanoparticles for continuous flow alkylations [J].

Balu, Alina M. ;

Pineda, Antonio ;

Obermayer, David ;

Romero, Antonio A. ;

Kappe, C. Oliver ;

Luque, Rafael .

RSC ADVANCES, 2013, 3 (37) :16292-16295

[2] Transesterfication of soybean oil catalyzed by sulfated ziconia [J].

Garcia, Camila Martins ;

Teixeira, Sergio ;

Marciniuk, Leticia Ledo ;

Schuchardt, Ulf .

BIORESOURCE TECHNOLOGY, 2008, 99 (14) :6608-6613

[3] Peroxovanadium-catalyzed oxidative esterification of aldehydes [J].

Gopinath, R ;

Barkakaty, B ;

Talukdar, B ;

Patel, BK .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (07) :2944-2947

[4] A catalytic oxidative esterification of aldehydes using V2O5-H2O2 [J].

Gopinath, R ;

Patel, BK .

ORGANIC LETTERS, 2000, 2 (05) :577-579

[5] Technologies for production of biodiesel focusing on green catalytic techniques: A review [J].

Helwani, Z. ;

Othman, M. R. ;

Aziz, N. ;

Fernando, W. J. N. ;

Kim, J. .

FUEL PROCESSING TECHNOLOGY, 2009, 90 (12) :1502-1514

[6] Characterizing the Kinetics of Nanoparticle-Catalyzed Reactions by Surface-Enhanced Raman Scattering [J].

Joseph, Virginia ;

Engelbrekt, Christian ;

Zhang, Jingdong ;

Gernert, Ulrich ;

Ulstrup, Jens ;

Kneipp, Janina .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (30) :7592-7596

[7] [IrCl(cod)]2-catalyzed direct oxidative esterification of aldehydes with alcohols [J].

Kiyooka, Syun-ichi ;

Wada, Yosuke ;

Ueno, Wada'Mahuyu ;

Yokoyama, Takeshi ;

Yokoyama, Reiko .

TETRAHEDRON, 2007, 63 (51) :12695-12701

[8] Calcium oxide as a solid base catalyst for transesterification of soybean oil and its application to biodiesel production [J].

Kouzu, Masato ;

Kasuno, Takekazu ;

Tajika, Masahiko ;

Sugimoto, Yoshikazu ;

Yamanaka, Shinya ;

Hidaka, Jusuke .

FUEL, 2008, 87 (12) :2798-2806

[9] N-heterocyclic carbene-catalyzed oxidation of unactivated aldehydes to esters [J].

Maki, Brooks E. ;

Scheidt, Karl A. .

ORGANIC LETTERS, 2008, 10 (19) :4331-4334

[10] Metal oxides as heterogeneous catalysts for esterification of fatty acids obtained from soybean oil [J].

Mello, Vinicius M. ;

Pousa, Gabriella P. A. G. ;

Pereira, Mirian S. C. ;

Dias, Ingrid M. ;

Suarez, Paulo A. Z. .

FUEL PROCESSING TECHNOLOGY, 2011, 92 (01) :53-57