Influence of the Li+ on the structure of the [Cu3(phis)3]3+ cation

被引：22

作者：

Vittal, JJ ^{[1
]}

Wang, XB ^{[1
]}

Ranford, JD ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 11期

关键词：

D O I：

10.1021/ic026311n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

When [Cu-3(phis)(3)](ClO4)(3), obtained from Cu(ClO4)(2) . 6H(2)O with the Na+ or K+ salt of the phis anion (Hphis = N-(2-pyridylmethyl)-L-histidine), is reacted with LiClO4, the tricopper cationic structure rearranged to accommodate a Li+ ion to form [(ClO4)Li{Cu-3(phis)(3)}](ClO4)(3) which can also be prepared directly by reacting Cu(ClO4)(2). 6H(2)O with the Li+ salt of the phis anion.

引用

页码：3390 / 3392

页数：3

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