Simultaneous determination of epinephrene and paracetamol at copper-cobalt oxide spinel decorated nanocrystalline zeolite modified electrodes

被引:33
作者
Samanta, Subhajyoti [1 ]
Srivastava, Rajendra [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Ropar 140001, Rupnagar, India
关键词
Spinets; Zeolite; Electrochemical sensor; Simultaneous determination; Paracetamol; Epinephrine; ELECTROCHEMICAL SENSOR; NANOCOMPOSITE MATERIAL; FOLIC-ACID; VOLTAMMETRIC DETERMINATION; SELECTIVE DETERMINATION; CHEMICAL-SYNTHESIS; CO3O4; NANOFIBERS; ASCORBIC-ACID; NOREPINEPHRINE; ACETAMINOPHEN;
D O I
10.1016/j.jcis.2016.04.049
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, CuCo2O4 and CuCo2O4 decorated nanocrystalline ZSM-5 materials were prepared. For comparative study, a series of MCo2O4 spinels were also prepared. Materials were characterized by the complementary combination of X-ray diffraction, N-2-adsorption, UV-visible, and electron microscopic techniques. A simple and rapid method for the simultaneous determination of paracetamol and epinephrine at MCo2O4 spinels modified electrodes is presented in this manuscript. Among the materials investigated in this study, CuCo2O4 decorated nanocrystalline ZSM-5 exhibited the highest electrocatalytic activity with excellent stability, sensitivity, and selectivity. Analytical performance of the sensor was demonstrated in the determination of epinephrine and paracetamol in the commercial pharmaceutical samples. (C) 2016 Elsevier Inc. All rights reserved.
引用
收藏
页码:126 / 135
页数:10
相关论文
共 38 条
[21]   Monitoring analgesic drug using sensing method based on nanocomposite [J].
Narang, Jagriti ;
Malhotra, Nitesh ;
Singh, Sandeep ;
Singh, Gajendra ;
Pundir, C. S. .
RSC ADVANCES, 2015, 5 (04) :2396-2404
[22]   A sandwich N-doped graphene/Co3O4 hybrid: an efficient catalyst for selective oxidation of olefins and alcohols [J].
Nie, Renfeng ;
Shi, Juanjuan ;
Du, Weichen ;
Ning, Wensheng ;
Hou, Zhaoyin ;
Xiao, Feng-Shou .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (32) :9037-9045
[23]   Facile preparation of β-Ni(OH)2-NiCo2O4 hybrid nanostructure and its application in the electro-catalytic oxidation of methanol [J].
Prathap, M. U. Anu ;
Satpati, Biswarup ;
Srivastava, Rajendra .
ELECTROCHIMICA ACTA, 2014, 130 :368-380
[24]   Electrochemical reduction of lindane (γ-HCH) at NiCo2O4 modified electrode [J].
Prathap, M. U. Anu ;
Srivastava, Rajendra .
ELECTROCHIMICA ACTA, 2013, 108 :145-152
[25]   Synthesis of NiCo2O4 and its application in the electrocatalytic oxidation of methanol [J].
Prathap, M. U. Anu ;
Srivastava, Rajendra .
NANO ENERGY, 2013, 2 (05) :1046-1053
[26]   Hydrothermal synthesis of CuO micro-/nanostructures and their applications in the oxidative degradation of methylene blue and non-enzymatic sensing of glucose/H2O2 [J].
Prathap, M. U. Anu ;
Kaur, Balwinder ;
Srivastava, Rajendra .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 370 :144-154
[27]   Molten salt synthesis and energy storage studies on CuCo2O4 and CuO•Co3O4 [J].
Reddy, M. V. ;
Yu, Cai ;
Jiahuan, Fan ;
Loh, Kian Ping ;
Chowdari, B. V. R. .
RSC ADVANCES, 2012, 2 (25) :9619-9625
[28]   Ordered mesoporous metal oxides: synthesis and applications [J].
Ren, Yu ;
Ma, Zhen ;
Bruce, Peter G. .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (14) :4909-4927
[29]   Ligand-assisted soft-chemical synthesis of self-assembled different shaped mesoporous Co3O4: efficient visible light photocatalysts [J].
Roy, Mouni ;
Ghosh, Sourav ;
Naskar, Milan Kanti .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (15) :10160-10169
[30]   Nanostructured anode materials for lithium ion batteries [J].
Roy, Poulomi ;
Srivastava, Suneel Kumar .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (06) :2454-2484